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伏安法教程
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/(英)卡普顿著
ISBN/ISSN：978-7-5100-9469-9
价格：RMB78.00
出版：北京 :世界图书北京出版公司 ,2015.08
载体形态： 页 ;26cm
丛编：289页
简介：伏安法是最基本的测量电阻的手段，也是电分析化学中最基本及简单的检测手段之一，在科学研究和生产实践中有广泛的应用。本书作为一本教材，详细地介绍了各种伏安法实验的设计和应用，并对伏安法中可能遇到的难点给出了严谨的解决方案。本书第一版系畅销教材，第二版在第一版的基础上增加了两章，以便读者更好的学习、理解。这套教材和习题，原版十分畅销，中科院长春应化所的彭章泉博士曾写信给作者，觉得此书非常好，拜读了10遍以上。中科院的万立俊研究员认为此书非常好，是物理化学领域的高端图书。目次：电化平衡和Ne。
中图分类号：O657.1 K835.21
责任者：弗洛伊德 ((Freud, Sigmund),) (1856-1939) 著 黄忠晶 编译 王银瓶 编译 黄巍 编译 弗洛伊德 ((Freud, S.),) (1856-1939) 著 顾闻 译
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目录：
Preface
1 Equilibrium Electrochemistry and the Nernst Equation
1.1 Chemical Equilibrium
1.2 Electrochemical Equilibrium: Introduction
1.3 Electrochemical Equilibrium: Electron Transfer at the Solution-Electrode Interface
1.4 Electrochemical Equilibrium: The Nernst Equation
1.5 Walther Hermann Nernst
1.6 Reference Electrodes and the Measurement of Electrode Potentials
1.7 The Hydrogen Electrode as a Reference Electrode
1.8 Standard Electrode Potentials and Formal Potentials
1.9 Formal Potentials and Experimental Voltammetry
1.10 Electrode Processes: Kinetics vs. Thermodynamics
2 Electrode Kinetics
2.1 Currents and Reaction Fluxes
2.2 Studying Electrode Kinetics Requires Three Electrodes
2.3 Butler-Volmer Kinetics
2.4 Standard Electrochemical Rate Constants and Formal Potentials
2.5 The Need for Supporting Electrolyte
2.6 The Tafel Law
2.7 Julius Tafel
2.8 Multistep Electron Transfer Processes
2.9 Tafel Analysis and the Hydrogen Evolution Reaction
2.10 B. Stanley Pons
2.11 Cold Fusion -- The Musical!
2.12 Why Are Some Standard Electrochemical Rate Constants Large but Others Slow? The Marcus Theory of Electron Transfer: An Introduction
2.13 Marcus Theory: Taking it Further. Inner and Outer Sphere Electron Transfer
2.14 Marcus Theory: Taking it Further. Adiabatic and Non-Adiabatic Reactions
2.15 Marcus Theory: Taking it Further. Calculating the Gibbs Energy of Activation
2.16 Relationship between Marcus Theory and Butler-Volmer Kinetics
2.17 Marcus Theory and Experiment. Success!
3 Diffusion
3.1 Fick's 1st Law of Diffusion
3.2 Fick's 2nd Law of Diffusion
3.3 The Molecular Basis of Fick's Laws
3.4 How Did Fick Discover His Laws?
3.5 The Cottrell Equation: Solving Fick's 2nd Law
3.6 The Cottrell Problem: The Case of Unequal Diffusion Coefficients
3.7 The Nernst Diffusion Layer
3.8 Mass Transfer vs. Electrode Kinetics: Steady-State Current-Voltage Waveshapes
3.9 Mass Transport Corrected Tafel Relationships
4 Cyclic Voltammetry at Macroelectrodes
4.1 Cyclic Voltammetry: The Experiment
4.2 Cyclic Voltammetry: Solving the Transport Equations
4.3 Cyclic Voltammetry: Reversible and Irreversible Kinetics
4.4 What Dictates'Reversible' and'Irreversible' Behaviour?
4.5 Reversible and Irreversible Behaviour: The Effect of Voltage Scan Rate
4.6 Reversible versus Irreversible Voltammetry: A Summary
4.7 The Measurement of Cyclic Voltammograms: Three Practical Considerations
……
5 Voltammetry at Microelectrodes
6 Voltammetry at Heterogeneous Surfaces
7 Cyclic Voltammetry: Coupled Homogeneous Kinetics and Adsorption
8 Hydrodynamic Electrodes
9 Voltammetry for Electroanalysis
10 Voltammetry in Weakly Supported Media: Migration and Other Effects
11 Voltammetry at the Nanoscale
Appendix: Simulation of Electrode Processes
Index
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